First and most important is you need to get out and practice with your archery equipment. You owe it to the animal to make the cleanest, most ethical kill you possibly can when presented with an opportunity. You can't just sight a bow in and forget about it. There are so many variables that into play when shooting a bow, that you need to practice and get that muscle memory going. That way, when a deer presents you with a shot, your body takes over and helps you remember what you need to do to make that perfect shot.
Second factor is scent control and paying attention to the wind. These two will help you out tremendously when trying to get close to a deer. Wash your clothes in scent free detergent and take a shower with scent free soap. Keep your clothes in a sealed container or plastic bag to keep them scent free. When hunting or preparing for a hunt, pay attention to wind direction and hunt from a stand where you expect deer to come in unwind from you.
Third, observe. If you can get out early before the season and scout, you can find the places where the deer travel. If you have a place where you can observe from a distance without disturbing your hunting area, this can be very effective in patterning deer.
Really, Bowhunting is all trail and error. But you can shift the odds in your favor by following the guidelines above.